Renji comes to the Material world in his gigai. Also Orihime's brother returns or is it really him? The new villians appear, but who are they targeting?

Commander Yamamoto gathers the other captains and tells them about what is being done to find Aizen. Meanwhile, back on Earth, Ichigo and the others are looking for clues to find Orihime. They recieve a phone call from a girl; she wants them to play a game and if they win she says she will return Orihime to them.

Ichigo, Ishida and Renji continue to play Rinrin's game. This time Rinrin wants them to play hide and seek in the museum.

After they arrive at school; Rinrin tells Ichigo and the others about the next game. One of them is an imposter and they must find out who it is before noon or everyone in their school will disappear.

RinRin, Cloud, Nova are on their final game. Orihime, Ishida, Renji, Kon and Ichigo make there attempt to save Chad. It turns out that Urahara has been the one behind it all, but then they find out there new enemies they must beat.

RinRin senses the presence of a Baunt, who are the new villains, and tells Ichigo about it . He arrives on the scene and starts to fight with the female Baunt. Later, someone he doesn't expect comes to help him.

Rukia and Ichigo continue to fight with the female Bounto, Yoshino, unitl a male Bounto, Ryou,shows up and takes her away. Ichigo, Rukia, Chad and Orihime then go to Ichigo's room to discuss the Bounto and what they know so far, which isn't alot. The next day at school; RinRin senses the presence of a Bounto and Ichigo and the others go after it.

While still fighting with Ryou, Ishida decided to trade himself for the life of an innocent woman. Suddenly, Yoshino appears and saves Ishida, taking him with her. Why did she help Ishida and what are her motives?

Ichigo and company keep an eye on Ishida at the hospital. When Ishida is attacked by two Bount who can control water, Ichigo and company try to break out of the closed hosiptal.

After escaping the hospital Ichigo and the others see that it is raining outside. Unfortunately this means they must continue fighting Hou and Ban, the two Bounts who control water.

Yoshino tells Ishida of her past with Jin, the leader of the Bount. Meanwhile Yachiru identifies one of the Bount as Ichinose, a former member of the 11th division.

Yoshino and Ishida are captured by a Bount named Koga and brought back to the Bount mansion. After the mod souls sense Ishida's spritual energy, Ichigo and the others go to the mansion to try and resue him.

While at the mansion Ichigo fights against Ryou and his doll Friido. Meanwhile Rukia and the mod souls run into trouble when they meet up with Ichinose, a former member of the 11th division.

Ichigo seems to be having trouble fighting Ichinose when Jin steps in and offers for Ichigo join them since he likes his spirit. Then Ichinose remembers when Zaraki defeated his captain and how he met Jin.

Mayuri shows some of the other captains the data he found on the Bount including data on a battle long ago between the Quincy and the Bount. Yoruichi tells Ichigo and the others about this information and they talk about it. While they are talking, Ganju shows up sensing Ichigo's depression about Jin. He and Renji then take Ichigo down to Urahara's underground training area to try and help Ichigo regain his confidence.

After leaving Urahara's place, Yoshino heads over to the remains of Bount mansion to confront Jin. While there Jin's explains that Yoshino doesn't know of her own importance to the Bount. Yoshino doesn't want anything to do with Jin's plan and decides to attack Jin, not caring whether she survives or not.

Ririn and Claude think that Ichigo isn't taking the Bount threat seriously so they dress up in special suits created by Urahara that look like the new Bount dolls and stage a fake attack. When Ichigo and Rukia's attacks become too much for them they try to remove the suits but they won't come off. What will happen now?

The Bount's new dolls have begun to attack living humans. When a team of shinigami from the covert ops can't seem to handle these dolls, Hitsugaya and a small group of others are sent down to the living world to help out. Meanwhile, Ichigo and the others still can't sense the Bount's whereabouts.

While wearing Urahara's new Bount sensor Ichigo is drawn to a construction site where his friend Keigo is having his soul sucked out by a few of the new Bount dolls. Ichigo stops the dolls and saves Keigo. Then Koga and his doll, Daruku, show up and start to fight with Ichigo.

While Ichigo is lying on the ground unable to move, Koga is reminded of the time Jin had him care for a young Bount named Cain. Meanwhile Rukia, Orihime and Cloud continue fighting against the female Bount, Yoshi.

The battle between Koga and Ichigo continues. Kira comes in and aids Ichigo in his battle aganist Koga and Daruku. Kira takes on Daruku while Ichigo tries to finish off Koga but can't. Koga then rethinks something and leaves. Yoshi conitunes her battle with Rukia, Orihime and Claude, until Mabashi comes in and starts to attack. He attacks Yoshi, and she runs just leaving him aganist Rukia, Orihime and Claude. How will they win this battle?

The battle between Rukia and Orihime conitunes on. As Orihime struggles to attack Rukia, who is under the control of Mabashi's doll Rizu. There only seems to be one choice: kill Rukia. Shūhei Hisagi shows up to aid Orihime. How will Orihime, Claude and Shūhei Hisagi save Rukia and defeat Mabashi.

Rangiku enters the real world and appears in front of Chad, Nova and Ururu. Soon enough they start fighting against the older Bount, Sawatari, and his doll Baura, who looks like a huge fish. Things become difficult when they realize that Baura has control over dimensions and can swallow an opponent whole sending them into another dimension.

Beginning where they left off in episode 86, Chad, Nova, and vice-captain of the 11th division, Matsumoto Rangiku, have one more plan to save Ururu from Baura. The plan works, but the second after, the Bounto decides he's had enough and vanishes. Meanwhile, in Soul Society, while third seat of the 10th division, Madarame Ikakku, is on watch, an invisible man invades Sereitei.

Ichigo and the gang regroup at Urahara's place. In the Soul Society Yamamoto tells Byakuya that his believes they have a traitor in their midst. Meanwhile Rangiku, Hisagi and Kira meet up with Yumichika in front of the Bount hideout. They enter the cave and run into some trouble when Ugaki and his doll Geselle set some traps for them.

Nemu, the 12th division vice captain, appears in front of Ishida and begins to attack him. After confirming her believe that Ishida lost his powers she asks him if he desires power. Meanwhile Ichigo and the others enter the Bount cave and start to fight against Ugaki's doll Geselle.

Ichigo and Renji continue through the Bountou's cave. As they see Yumichika, they try to save him. But Ugaki and his doll Geselle, attack. Ugaki shows his true doll's form, and starts to attack. Renji decides to fight alone, because of him seeing Yumichika suffering. He releases his ban-kai, and Ugaki starts to attack chickenly. Ugaki is told to hurry it up, because something is happening to Ishida.He tries to do his final attack, but Renji does a new move and hurts Geselle. Geselle freaks out and starts attacking randomly. Geselle turns on Ugaki and kills him, and both die. After all that is finished, Ichigo finds the Bountous. Jin wants to test his new powers as the other Bountou and Ichinose prepare the gate. Jin tells Ichigo their plan and why they want to go to the Soul Society.

After knowing Kariya's real evil plan, Ichigo finally achieves Bankai in the real world. He and Kariya start fighting, but they are interrupted by Ishida's surprising entrance - along side with the gang (Chad, Inoue, and Rukia). Later on, it becomes clear why Kariya kidnapped Ishida at the beginning. Ishida does something surprising causing the Bountos to pass the portals to Soul Society, but he explains why. The episode ends with everyone deciding to follow the Bountos to Soul Society and defeat them there.